What is surface modification (hydro / oleo – phobic / philic) ?

Surface modification is the act of modifying the surface of a material by bringing physical, chemical or biological characteristics different from the ones originally found on the surface of a material.

Hydrophobic effect

The term hydrophobic means water (hydro) fearing (phobic). In chemistry, hydrophobicity is the physical property of a molecule known as a hydrophobe that is repelled from a mass of water. This is purely due to the absense of attraction without involving any repulsive force. Hydrophobic effects can be achieved by the application of alkylsilanes on a wide range of mineral substrates:

  • Porous surfaces, such as concrete, natural stone to create water repellency
  • Mineral fillers and pigments to improve dispersibility and compatibility in organic polymers

 

Oleophobic effect

The term oleophobic means oil (oleo) fearing (phobic) which also sometimes called lipophobia. It is a chemical property of chemical compounds which means “fat rejection”, literally “fear of fat”. Oleophobic or lipophobic compounds are those not soluble in lipids or other non-polar solvents. From the other point of view, they do not absorb fats. Oleophobic effects can be achieved by the application of fluoroalkylsilanes on a wide range of substrates.

  • Smooth surfaces, such as glass and ceramic to create durable anti-stick and easy-to-clean properties
  • Porous surfaces, such as concrete, natural stone to create easy-to-clean and anti-graffiti properties
  • Cellulose materials, such as wood to achieve long lasting water and oil repellence

Hydrophilic effect

The term hydrophillic means water (hydro) loving (phillic). Hydrophilic substances (ex: salts) can seem to attract water out of the air. Sugar is also hydrophilic, and like salt is sometimes used to draw water out of foods. Hydrophilic effects on mineral materials can be achieved by the use of silanes containing hydrophilic functionalities, such as amino, polyethylene oxide, and epoxy. These properties improve dispersibility in polar solvents, water, and polar polymers and allow higher filler loadings.

Organophilic effect

Organophillic basically means a chemical or molecular orientation favoring the attraction of hydrocarbons or materials which are miscible in hydrocarbons. Organophilic materials are characterized by weak dipole moments. They are basically immiscible in water. Organophilic effect on inorganic materials can be achieved by using a number of organofunctional silanes.

  • Many applications benefit from these properties:
  • Compatibility between filler/reinforcement and organic polymer
  • Improve processing
  • Higher filler loadings
  • Improved wetting of the inorganic material by the polymer